A 50.0 mL solution of 0.129 M KOH is titrated with 0.258 M HCl. Calculate the pH of the solution after the addition of each of the given amounts of HCl.
A) 0.00ml
B)7.00ml
C)12.5ml
D)18.0ml
E)24.0ml
F)25.0ml
G)26.0ml
H)29.0ml

please show work with steps .

Answers

Answer 1

Answer:

A- pH = 13.12

B- pH = 12.91

C- pH = 12.71

D- pH = 12.43

E- pH = 11.55

F- pH = 7

G- pH = 2.46

H- pH = 1.88

Explanation:

This is a titration of a strong base with a strong acid. The neutralization reaction is: KOH (aq) + HCl (aq) →  H₂O(l) + KCl(aq)

Our pH at the equivalence point is 7, because we have made a neutral salt.

To determine the volume at that point we state the formula for titration:

mmoles of base = mmoles of acid

Volume of base  . M of base = Volume of acid . M of acid

50mL . 0.129M = 0.258 M . Volume of acid

Volume of acid = (50mL . 0.129M) / 0.258 M →  25 mL (Point F)

When we add 25 mL of HCl, our pH will be 7.

A- At 0 mL of acid, we only have base.

KOH → K⁺ + OH⁻

[OH⁻] = 0.129 M

To make more easy the operations we will use, mmol.

mol . 1000 = mmoles → mmoles / mL = M

- log 0.129 = 0.889

14 - 0.889 = 13.12

B-  In this case we are adding, (7 mL . 0.258M) = 1.81 mmoles of H⁺

Initially we have  0.129 M . 50 mL = 6.45 mmoles of OH⁻

1.81 mmoles of H⁺ will neutralize, the 6.45 mmoles of OH⁻ so:

6.45 mmol - 1.81 = 4.64 mmoles of OH⁻

This mmoles of OH⁻ are not at 50 mL anymore, because our volume has changed. (Now, we have 50 mL of base + 7 mL of acid) = 57 mL of total volume.

[OH⁻] = 4.64 mmoles / 57 mL = 0.0815 M

- log 0.0815 M = 1.09 → pOH

pH = 14 - pOH → 14 - 1.09 = 12.91

C- In this case we add (12.5 mL . 0.258M) = 3.22 mmoles of H⁺

Our initial mmoles of OH⁻ would not change through all the titration.

Then 6.45 mmoles of OH⁻ are neutralized by 3.22 mmoles of H⁺.

6.45 mmoles of OH⁻ - 3.22 mmoles of H⁺ = 3.23 mmoles of OH⁻

Total volume is: 50 mL of base + 12.5 mL = 62.5 mL

[OH⁻] = 3.23 mmol / 62.5 mL = 0.0517 M

- log  0.0517 = 1.29 → pOH

14 - 1.11 = 12.71

D- We add (18 mL . 0.258M) = 4.64 mmoles of H⁺

6.45 mmoles of OH⁻ are neutralized by 4.64 mmoles of H⁺.

6.45 mmoles of OH⁻ - 4.64 mmoles of H⁺ = 1.81 mmoles of OH⁻

Total volume is: 50 mL of base + 18 mL = 68 mL

[OH⁻] = 1.81 mmol / 68 mL = 0.0265 M

- log  0.0265 = 1.57 → pOH

14 - 1.57 = 12.43

E- We add (24 mL . 0.258M) = 6.19 mmoles of H⁺

6.45 mmoles of OH⁻ are neutralized by 6.19 mmoles of H⁺.

6.45 mmoles of OH⁻ - 6.19 mmoles of H⁺ = 0.26 mmoles of OH⁻

Total volume is: 50 mL of base + 24 mL = 74 mL

[OH⁻] = 0.26 mmol / 74 mL = 3.51×10⁻³ M

- log  3.51×10⁻³  = 2.45 → pOH

14 - 2.45 = 11.55

F- This the equivalence point.

mmoles of OH⁻ = mmoles of H⁺

We add (25 mL . 0.258M) = 6.45 mmoles of H⁺

All the OH⁻ are neutralized.

OH⁻  +  H⁺  ⇄   H₂O              Kw

[OH⁻] = √1×10⁻¹⁴   →  1×10⁻⁷  →  pOH = 7

pH → 14 - 7 = 7

G- In this case we have an excess of H⁻

We add (26 mL . 0.258M ) = 6.71 mmoles of H⁺

We neutralized all the OH⁻ but some H⁺ remain after the equilibrium

6.71 mmoles of H⁺ - 6.45 mmoles of OH⁻ = 0.26 mmoles of H⁺

[H⁺] = 0.26 mmol / Total volume

Total volume is: 50 mL + 26 mL → 76 mL

[H⁺] = 0.26 mmol / 76 mL → 3.42×10⁻³ M

- log 3.42×10⁻³ = 2.46 → pH

H- Now we add (29 mL . 0.258M) = 7.48 mmoles of H⁺

We neutralized all the OH⁻ but some H⁺ remain after the equilibrium

7.48 mmoles of H⁺ - 6.45 mmoles of OH⁻ = 1.03 mmoles of protons

Total volume is 50 mL + 29 mL = 79 mL

[H⁺] = 1.03 mmol / 79 mL → 0.0130 M

- log 0.0130 = 1.88 → pH

After equivalence point, pH will be totally acid, because we always have an excess of protons. Before the equivalence point, pH is basic, because we still have OH⁻ and these hydroxides, will be neutralized through the titration, as we add acid.

Answer 2

The pH value is given by 14 less the logarithm of the hydronium ion

concentration or the hydrogen ion concentration in the solution.

Responses (approximate values):

The pH values are;

A) 13.11

B) 12.91

C) 12.71

D) 12.42

E) 11.54

F) 7

G) 2.469

H) 1.884

Which is used to find the pH of the solution?

A) Concentration of the KOH = 0.129 M

Amount of HCl added = 0.00 ml

The pH = -log[H⁺] = 14 - pOH

pOH = -log[OH⁻]

Which gives;

pH = 14 - (-log[OH⁻] )

pH = 14 - (-log(0.129)) ≈ 13.11

B) Volume of acid added = 7.00 mL = 0.007 L

Concentration of the acid = 0.258 M HCl

Number of moles of acid, H⁺ = 0.007 × 0.258 moles = 0.001806 moles

Number of moles of KOH remaining, OH⁻= 0.05 × 0.129 - 0.001806 = 0.004644

Number of moles of OH⁻ = 0.004644 moles

[tex]Concentration, \ [OH^-] = \dfrac{0.004644 \, moles}{0.05 7 \, L} \approx \mathbf{ 0.0815 \, M}[/tex]

pH of solution = 14 - (-log(0.0815)) ≈ 12.91

C) 12.5 mL HCl contains, 0.0125 × 0.258 moles = 0.003225 moles

OH⁻ remaining = 0.05 × 0.129 - 0.003225 = 0.003225 moles

[tex]Concentration \ of \ [OH^-]= \dfrac{0.003225\, moles}{(0.05 + 0.0125) \, L} = \mathbf{0.0516 \, M}[/tex]

pH of solution = 14 - (-log(0.0516)) ≈ 12.71

D) 18.0 mL HCl contains, 0.018 × 0.258 moles = 0.004644 moles

OH⁻ remaining = 0.05 × 0.129 - 0.004644 = 0.001806 moles

[tex]Concentration \ of \ [OH^-] = \dfrac{0.001806\, moles}{(0.05 + 0.018) \, L} \approx \mathbf{0.0266\, M}[/tex]

pH of solution = 14 - (-log(0.0266)) ≈ 12.42

E) 24.0 mL HCl contains, 0.024 × 0.258 moles = 0.006192 moles

OH⁻ ion remaining = 0.05 × 0.129 - 0.006192 = 0.000258 moles

[tex]Concentration \ of \ [OH^-] = \dfrac{0.000258\, moles}{(0.05 + 0.024) \, L} \approx \mathbf{0.0035\, M}[/tex]

pH of solution = 14 - (-log(0.0035)) ≈ 11.54

F) 25.0 mL HCl contains, 0.025 × 0.258 moles = 0.00645 moles

[OH⁻] remaining = 0.05 × 0.129 - 0.00645 = 0 moles

[tex]Concentration \ of \ [OH^-] = \dfrac{0\, moles}{(0.05 + 0.024) \, L} \approx 0\, M[/tex]

Therefore;

Number of moles of KOH = 0, or the solution is neutralized

[OH⁻] = [H⁺]

Which gives;

pH = pOH = 7

G) 26.0 mL HCl contains, 0.026 × 0.258 moles = 0.006708 moles

[OH⁻] remaining = 0.05 × 0.129 - 0.006708 = -0.000258 moles

Therefore

Number of moles of H⁺ = 0.000258

[tex]\mathbf{Concentration} \ of \ \mathbf{[H^+] }= \dfrac{0.000258\, moles}{(0.05 + 0.026) \, L} \approx 0.003395\, M[/tex]

pH of solution = (-log(0.003395)) ≈ 2.469

H) 29.0 mL HCl contains, 0.029 × 0.258 moles = 0.007482 moles

H⁺ remaining = 0.007482 - 0.05 × 0.129 = 0.001032 moles

Therefore

Number of moles of H⁺ = 0.001032

[tex]Concentration \ of \ [H^+] = \mathbf{ \dfrac{0.001032\, moles}{(0.05 + 0.029) \, L}} \approx 0.01306\, M[/tex]

pH of solution = (-log(0.01306)) ≈ 1.884

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Related Questions

If potassium reacts so dangerously with water, and people are mostly made of water, why can we eat bananas without blowing up?

Answers

Answer:

A banana, like most other lifeforms, is about 70% water, and all the potassium it contains already exists in the form of K+ ions dissolved in water. Which is why bananas do not explode in water, or spontaneously combust.

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Explanation:

Which is an acceptable Lewis structure for a diatomic nitrogen molecule?
OA NEN
OB.
N
N
O C.
:N
N:
OD.
NEN
OENEN

Answers

Answer:

:N:::N:

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An acceptable Lewis structure for a diatomic nitrogen molecule is

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What is Lewis structure for a diatomic nitrogen molecule?

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on analysis an ammonium salt of an alkanoic acid gave 60.5% C and 6.5% H if 0.309g of the salt yield 0.0313g of Nitrogen determine the empirical formula of the salt [ H = 1, C =12, N = 14, O= 16]​

Answers

Answer: C7H9NO2

Explanation:

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= 10.1%

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= 22.9

C; 60.5/12 H; 6.5/1 N; 10.1/14 O; 22.9/16

C; 5.04/0.72 H; 6.5/0.72 N; 0.72/0.72 O; 1.43/0.72

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Which of the following statements best goes with the Law of Conservation of Energy?
all energy conversions are 100% efficient
O all energy from the sun is transferred to organisms directly by the 10% rule
O all of the sun's energy is either transformed into kinetic energy, and eventually heat energy
O all matter cannot be created or destroyed

Answers

Answer:

all letter cannot be created or destroyed just transformed

What is the atomic weight of Mercury?

Answers

Answer:

Not sure if I'm correct, but I think it's 200.59 u

Answer:

The answer is 200.59 u

Explanation:

Mercury has a mass of 3.3 x 1023kilograms. This mass is contained in a volume of 14.6 billion cubic miles (60.8 billion cubic km). The mass and volume of Mercury is only about 0.055 times that of Earth

What is geberal formula for alkane? ​

Answers

Answer:

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Like C4H10

n = 4

CnH2n+2

C4H2×4+2

C4H10

one reaction that produces hydrogen gas can be represented by the unbalanced chemical equation Mg(s)+HCI(aq) -> MgCI(aq)+H2(g). What is the mass of HCI is consumed by the reaction of 3.25 mol of magnesium?

Answers

Answer:

128 g HCl

General Formulas and Concepts:

Math

Pre-Algebra

Order of Operations: BPEMDAS

Brackets Parenthesis Exponents Multiplication Division Addition Subtraction Left to Right

Chemistry

Atomic Structure

Reading a Periodic Table

Stoichiometry

Reaction Mole RatiosUsing Dimensional AnalysisExplanation:

Step 1: Define

[RxN - Unbalanced] Mg (s) + HCl (aq) → MgCl (aq) + H₂ (g)

[RxN - Balanced] 2Mg (s) + 2HCl (aq) → 2MgCl (aq) + H₂ (g)

[Given] 3.25 mol Mg

[Solve] x g HCl

Step 2: Identify Conversions

[RxN] 2 mol Mg → 2 mol HCl

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[PT] Molar Mass of Cl - 35.45 g/mol

Molar Mass of HCl - 1.01 + 35.45 = 36.46 g/mol

Step 3: Stoich

[S - DA] Set up:                                                                                                 [tex]\displaystyle 3.25 \ mol \ Mg(\frac{2 \ mol \ HCl}{2 \ mol \ Mg})(\frac{36.46 \ g \ HCl}{1 \ mol \ HCl})[/tex][S - DA] Multiply/Divide [Cancel out units]:                                                    [tex]\displaystyle 127.61 \ g \ HCl[/tex]

Step 4: Check

Follow sig fig rules and round. We are given 3 sig figs.

127.61 g HCl ≈ 128 g HCl

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Answers

Answer:

The answer is A.Newton's First law

What would be the structural formula for sodium fluoride? (NaF)

Answers

Answer:

Formula and structure: The chemical formula of sodium fluoride is NaF and its molar mass is 41.99 g/mol. It is a simple ionic compound, made of the sodium (Na +) cation and fluoride (F -) anion. The solid salt exists as cubic crystals similar to the crystal structure of sodium chloride (NaCl).

Explanation:

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Answers

Answer:

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Answer:

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Single replacement reaction is a chemical reaction in which more reactive element displaces the less reactive element from its salt solution.

A more reactive element is one which can easily lose or gain electrons as compared to the other element.

As Magnesium is more reactive than tin, it can easily displace tin from its salt solution [tex](SnCl_3)[/tex] and form magnesium chloride and tin in elemental form.

The balanced chemical equation is:

[tex]3Mg(s)+2SnCl_3(aq)\rightarrow 3MgCl_2(aq)+2Sn(s)[/tex]

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Answers

Answer:

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Answers

Answer:

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Explanation:

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• as it sits on top of a building that is 50 meters tall.
• as it is half-way through a fall off a building that is 50 meters tall and travelling 19.8 meters per second.
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What is the potential energy of the ball as it is half-way through the fall (25 meters high)?

Answers

I think the answer is “ as it sits on top of a building that is 50 meters tall. “

what is the purpose of sand bath in preparation of ethane​

Answers

Answer:

The sand bath spreads the heat out so that the flask is heated evenly. This reduces the chance of the flask breaking and ensures that there are no hot spots in the reaction mixture which could lead to excessive charring,

Explanation:

WRITE A 3-4 SENTENCE SUMMARY ABOUT ATOMS.

Answers

Answer:

An atom is the smallest unit of matter that retains all of the chemical properties of an element. Atoms combine to form molecules, which then interact to form solids, gases, or liquids. For example, water is composed of hydrogen and oxygen atoms that have combined to form water molecules.

Explanation:

Answer:

Atom is the smallest particle in the universe. An atom is made up of sub-atomic particles. They are the protons (positively charged particle), electrons (negatively charged particles) and neutrons neutrally charged particles). The lightest atom ever known is Hydrogen atom. An atom is electrically neutral. When a atom looses or gains and electrons it is called an ions.

g When water and perchloric acid (HClO4) are mixed, heat is released. The resulting solution is not an ideal solution, in terms of Raoult’s Law. How should the boiling point and the vapor pressure of a solution of HClO4 in H2O differ from what is expected for an ideal solution? A) boiling point higher than expected, vapor pressure lower than expected B) boiling point higher than expected, vapor pressure higher than expected C) boiling point lower than expected, vapor pressure lower than expected D) boiling point lower than expected, vapor pressure higher than expected E) boiling point and vapor pressure are both the same as expected for an ideal solution

Answers

Answer:

A) boiling point higher than expected vapor pressure lower than expected.

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When water is introduced with heat it vaporize at a temperature of 100 degree centigrade. When hydrochloric acid is added to the water its boiling point of water increases slightly. The difference in the boiling point is due to the presence of heavier molecules in acid.

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Answers

Answer:

Tell students that sometimes when two (or more) substances are mixed together, a change occurs and another substance (or substances) is created. This is called a chemical reaction. Gas may form, heat may be produced, and color may change. These types of changes indicate that a chemical reaction has occurred.

Which statement describes the movement of the medium by a transverse wave?


A. at an obtuse angle to the wave

B. parallel to the wave

C. at a right angle to the wave

D. at an acute angle to the wave

Answers

Answer:

A

Explanation:

But I'm not sure just my instinct

The statement that described the movement of the medium via the transverse wave should be that it should be parallel to the wave.

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It is the waves in which the motion considered all the points that should be on the wave oscillate along the paths at the right angles with respect to the wave of the direction. An example of this kind of wave should be electromagnetic, etc. Here, the movement should be parallel to the wave.

Hence, the correct option is b.

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A 1 mL sample weighs 4 g, the density of the sample is

Answers

ok so density is mass volume

D=m/v

mass in this case is 4 g
volume is either mL or cm^3 and in this case its 1 mL so

D=4 g/1 mL
D=4 g/mL

A 508-g sample of sodium bicarbonate (NaHCO3) contains how many moles of sodium bicarbonate (NaHCO3)?

Answers

molar mass = (22.99) + (1.01) + (12.01) + 3(16.00)

molar mass = 84.01 g/mol

//

(508g)(1 mol/84.01 g) = 6.0

There are 6.0 moles of sodium bicarbonate

A 508-g sample of sodium bicarbonate (NaHCO3) contains 0.6 moles of sodium bicarbonate (NaHCO3)

What is mass?

Mass is defined as a dimensionless quantity representing the amount of matter in a particle or object. The SI unit of mass is kg.

Mole is defined as a standard scientific unit for measuring large quantities of very small entities

Molar mass = 22.99 + 1.01 + 12.01 + 3x16.00

                   = 84.01 g/mole

Moles of NaHCO3

= 508 g x 1 mole / 84.01

= 6.0 moles

Thus, 508-g sample of sodium bicarbonate (NaHCO3) contains 0.6 moles of sodium bicarbonate (NaHCO3)

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In an experiment, 20cm^3 of 0.2dm^3 NaOH reacted with 32.0cm^3 of H2SO4 solution. Calculate the concentration of the H2SO4 in a) mol dm^-3 and b) g dm^-3​

Answers

Answer:

A. 0.0625 moldm¯³

B. 6.125 gdm¯³

Explanation:

We'll begin by writing the balanced equation balance equation for the reaction. This is illustrated below:

2NaOH + H₂SO₄ —> Na₂SO₄ + 2H₂O

From the balanced equation above,

The mole ratio of the acid, H₂SO₄ (nₐ) = 1

The mole ratio of the base, NaOH (n₆) = 2

A. Determination of the concentration of the acid in moldm¯³.

Volume of base, NaOH (V₆) = 20 cm³

Concentration of base, NaOH (C₆) = 0.2 moldm¯³

Volume of acid, H₂SO₄ (Vₐ) = 32 cm³

The mole ratio of the acid, H₂SO₄ (nₐ) = 1

The mole ratio of the base, NaOH (n₆) = 2

Concentration of acid, H₂SO₄ (Cₐ) =?

CₐVₐ / C₆V₆ = nₐ / n₆

Cₐ × 32 / 0.2 × 20 = 1 / 2

Cₐ × 32 / 4 = 1 / 2

Cross multiply

Cₐ × 32 × 2 = 4 × 1

Cₐ × 64 = 4

Divide both side by 64

Cₐ = 4 / 64

Cₐ = 0.0625 moldm¯³

Therefore, concentration of the acid in moldm¯³ is 0.0625 moldm¯³

B. Determination of the concentration of the acid in gdm¯³.

Concentration (moldm¯³) = 0.0625 moldm¯³

Concentration (gdm¯³) =?

Next, we shall determine the molar mass of the acid, H₂SO₄. This can be obtained as follow:

Molar mass of H₂SO₄ = (2×1) + 32 + (4×16)

= 2 + 32 + 98

= 98 g/mol

Finally, we shall determine the concentration of the acid in gdm¯³. This can be obtained as follow:

Concentration (moldm¯³) = 0.0625 moldm¯³

Molar mass of H₂SO₄ = 98 g/mol

Concentration (gdm¯³) =?

Conc. (moldm¯³) = conc. (gdm¯³) / Molar mass

0.0625 = Conc. (gdm¯³) / 98

Cross multiply

Conc. (gdm¯³) = 0.0625 × 98

Conc. (gdm¯³) = 6.125 gdm¯³

Thus, the concentration of the acid in gdm¯³ is 6.125 gdm¯³

In humans, normal color perception (N) dominates the expression of color blindness (n), and both of these genes are carried on the X chromosome (XN or Xn). A woman with normal color vision has a color-blind father. Her husband is also color-blind.

a. What is the genotype of the colorblind man? ____
b. What is the genotype of the woman? ______
c. What is the probability of her daughter to be colorblind? __________%
d. What is the probability of her sons to be colorblind? _________%


WHO CAN HELP ME

Answers

Answer:

a: Nn or XN

b: Nn or Xn

c: 75%

d: 50%

Explanation:

Other Questions
Explain the process of protein synthesis be sure to include the following terms ribosome and mRNA TRNA codon and peptide bonds One leg of a right triangle is 6 units long, and its hypotenuse is 12 units long. What is the length of the other leg? Round to the nearest whole number. you are cinsidering investing in a peice of equipment to implement a cost cutting proposal the pre tax cost reduction is expected to equal $41.67 for each of the three years of the project's life. The equipment has an initial cost of $125 and belongs in a 20% CCA class. Assume a 34% tax bracket, a discount rate of 15%, and a salvage value of zero. If the equipment is sold to another company at the end of year 3 for $20, what is the PI? Which of the following is NOT a true statment regarding the Alaris MedSystem III? The table shows a probability distribution P(X) for a discrete random variable X. What is P(X>2)? Complete each statement by underlining the correct term or phrase in the brackets. A receptor is a [protein / fatty acid] to which a molecule binds. the tendency to see members of out-groups as very similar to each other is called: ___________________ homology includes amino acids and DNA sequencing, while homology includes features that are similar in their anatomy a locked section of fault is often identified by the existence of __________ there. TRUE OR FALSE you are more likely to find an item by using a binary search than by using a linear search. which of the following can be used to add visual elements with information that is part of the message? "jem condescended to take me to school the first day, a job usually done by ones parents...." according to the context, condescended means _____. Visual aids should serve a purpose beyond simply meeting audience desires. What is one of the purposes listed in the textbook?A.) To reinforce or emphasize a point.B.) To make the presentation more visually appealing.C.) To provide something for the audience to focus on when they get bored. Reread lines 49. Identify two examples of parallelism in these lines and describe the effect of each. order the following species found in the fossil record based on their age, starting with the oldest on top. Use the table of Consumer Price Index values and subway fares to determine a line of regression that predicts the fare when the CPI is given. CPI 30.2 48.3 112.3 162.2 191.9 197.8 Subway Fare 0.15 0.35 1.00 1.35 1.50 2.00 O j = 0.00955 0.124x O =-0.0331 +0.00254x O =-0.124 + 0.00955x O = 0.00254 0.0331x Using literature, describe how 31P NMR or other nuclei can be used for other quantitative measurements other than structure elucidation. Cite your source, which must be a primary resource. This is for Inorganic Chemistry Lab people demand freedom of speech as a compensation for the freedom of thought which they seldom use. tony and pepper are directors and shareholders of stark software, inc. tonys written authorization to pepper to vote tonys shares at a stark shareholders meeting is Create two lists. On one list, record the many ways that schools around 1900 are similar to the school you attend. On the otherecord the many differences.