Draw the major product formed in the reaction of an epoxide with methoxide in methanol.

Answers

Answer 1
Describe epoxide.

the major product of the reaction is (2S,3R)-3-methoxy-3-methylpentan-2-ol.

Epoxy, epoxide, oxirane, and ethoxyline are all names for substances that contain the epoxide functional group. Oxides are a common name for simple epoxides. Consequently, ethylene oxide is the epoxide of ethylene (C2H4).

Reaction  and explanation.

In order to answer this question, we must draw the main product and the studio chemistry. Yeah. Therefore, we will begin by drawing the reactant, which is an oxide.

As with this structure. Therefore, C. S. is applied to this epoxy side. Three ohs and two hash marks. As a result, the oxygen will be presented with the lone pair on the initial stage. And after that, we will receive the prototype for a thirty-plus-year-old product. And everything else will proceed as usual, even this.

Now this bond will be severed, and three miners from O. C. S. will attack from the back, in which case we will receive the finished product as seen here.

for more information about epoxide  visit:

brainly.com/question/14058900

#SPJ4

Draw The Major Product Formed In The Reaction Of An Epoxide With Methoxide In Methanol.
Answer 2

(2S,3R)-3-methoxy-3-methylpentan-2-ol is the reaction's main product. 

Epoxide functional group-containing compounds go by the names epoxy, epoxide, oxirane, and ethoxyline. Simple epoxides are frequently referred to as oxides. As a result, ethylene oxide is ethylene's epoxide (C2H4).Reaction and justification.We must illustrate the primary product and the studio chemistry in order to provide a response. As a result, we shall start by drawing the oxide reactant.

similar to this structure C. S. is therefore applied to this epoxy side. Two hash marks and three OHs. As a result, on the initial stage, the oxygen will be presented with the sole pair. Then we will get the prototype for a product that has been around for more than thirty years. And even this will occur according to plan.

This relationship will now be broken, and three O. C. S. miners will assault from behind, resulting in the finished article you see here.

To learn more about epoxide visit:

https://brainly.com/question/14058900

#SPJ4


Related Questions

difference between solute and solvent​

Answers

When one substance dissolves into another, a solution is formed.  A solution is a homogeneous mixture consisting of a solute dissolved into a solvent .  The solute is the substance that is being dissolved, while the solvent is the dissolving medium.  Solutions can be formed with many different types and forms of solutes and solvents.

Explanation:

solute are substance that dissolve in solvent

solvent are substance that dissolve solute

what is the name of this branched alkane?

Answers

Answer:

Explanation:

3-methyl pentane.

Answer:

the answer is methyl pentane

PLEASE ANSWER QUICK... WILL GIVE BRAINLIEST

The relative humidity is 100%, and the temperature is hot. In a few sentences, explain how the weather would change if the temperature drops and becomes cool.

Answers

Answer:

Humdity would decrease hence temprature would do the same, hence tundra are called deserts at times.

Explanation:

If you keep on decreasing the temperature without changing the air's moisture content significantly, eventually you'll reach 100 percent relative humidity, and then water vapor will start to condense to form dew.

What happens when humidity is at 100% and the temperature drops?

Dew Point. When the relative humidity reaches 100 percent, dew forms. Dew point refers to the temperature at which air reaches saturation by water molecules. Warmer air can hold more water molecules, and as that warm air cools, it loses water vapor in the form of condensation.

What happens when it reaches 100% relative humidity?

When relative humidity reaches 100 percent or is saturated, moisture will condense, meaning the water vapor changes to liquid-vapor. Thus, the saturation level of air is related to the air's temperature.

Learn more about relative humidity here https://brainly.com/question/21494654

#SPJ2

Classify the following alcohol as primary,
secondary or tertiary.
A. primary
ОН
B. secondary
C. tertiary
Enter

Answers

The classification of the alcohols gives;

Compound 1 - Primary alcoholCompound 2 - Tertiary alcoholCompound 3 - Secondary alcoholCompound 4 - Secondary alcohol

What are alcohols?

Organic compounds occurs in families. The family of compounds is called a homologous series. The homologous series always have a functional group. The functional group is the atom, group of atoms or bond that is responsible for the chemical reactivity of the members of a given homologous series.

Now we know that the alcohols are those organic compounds that contains the -OH group. The could be aliphatic or alicyclic compounds. We shall now proceed to name the kind of alcohols that each of the compounds shown are;

Compound 1 - Primary alcoholCompound 2 - Tertiary alcoholCompound 3 - Secondary alcoholCompound 4 - Secondary alcohol

Learn ore about alcohols:https://brainly.com/question/4698220

#SPJ1

Plzzzzz I need help ASAP

Answers

Answer:

i) B, ii) A, iii) C

Explanation:

give me brainliest

The enthalpy of fusion for Al is 10.7 kJ/mol. What is the energy change when 30.8 g of Al solidifies at 660°C?

Answers

The enthalpy of fusion for Al is 10.7 kJ/mol. -12.2 kJ is the energy change when 30.8 g of Al solidifies at 660°C.

What is Enthalpy of Fusion ?

The amount of energy needed to change 1 mole of substance under state change at constant temperature and pressure is called enthalpy of fusion. It is also known as Latent heat of fusion. Unit of enthalpy of fusion is kJ/mol.

How to find the change in energy ?

To find the change in energy use this expression:

q = n ΔH

where

q = Energy change

n = number of moles

ΔH = Molar enthalpy

Number of moles (n) = [tex]\frac{\text{Given mass}}{\text{Molar mass}}[/tex]

                                  = [tex]\frac{30.8\ g}{26.98\ \text{g/mol}}[/tex]

                                  = 1.141 mol

Now put the values in above formula we get

q = - n ΔH                    [Negative sign is used because Al solidifies here]

  =  - (1.141 mol × 10.7 kJ/mol)

  = -12.2 kJ

Thus from the above conclusion we can say that The enthalpy of fusion for Al is 10.7 kJ/mol. -12.2 kJ is the energy change when 30.8 g of Al solidifies at 660°C.

Learn more about the Latent heat of fusion here: https://brainly.com/question/87248

#SPJ1

Suppose a aqueous solution of phosphoric acid () is prepared. Calculate the equilibrium molarity of . You'll find information on the properties of phosphoric acid in the ALEKS Data resource.

Answers

The equilibrium molarity HPO²₄- = 6.2 x 10⁻⁸M See the explanation below.

What is Equilibrium Molarity?

The molar concentration of a certain species in a solution is known as equilibrium molarity.

What is the calculation showing the above answer?

The initial concentration H₃PO₄ = 0.31 M

Kₐ₁ = 6.92 x 10⁻³ (See Image 1 attached)

Kₐ₁ = [H⁺][tex]_{eq}[/tex][H₂PO₄-][tex]_{eq}[/tex] / [H₃PO₄][tex]_{eq}[/tex]

6.92⁻³ x 10 = [(x) * (x)] / (0.31 M - x)

Solving for x, x = 0.043 M

[H+] = x = 0.043 M

[H₂PO₄-] = x = 0.043 M 0.0429805

Kₐ₂ = 6.2 x 10⁻⁸

See the second attached table

Kₐ₂ = [H+][tex]_{eq}[/tex] [HPO₄²-]eq / [H₂PO₄-]eq

6.2 x 10⁻⁸ = [(0.043 M + x) * (x)] / (0.043 M - x)

Solving for x, x = 6.2 x 10⁻⁸ M

[H₂PO₄-]eq = x = 6.2 x 10⁻⁸ M

Learn more about equilibrium molarity at;
https://brainly.com/question/14469428
#SPJ1

Describe the energy of the products in comparison to the energy the atoms had when the were wandering around the room free.

Answers

Answer: The atoms of the solid products are tightly packed whereas those in gas are loose.

Explanation:

Atoms in the solid structure are linked to each other by strong force of attraction and they collectively form an three-dimensional structure. The binding of the atoms form the shape of the solid product. The gas exhibit free atoms in it. The atoms are not linked to one another by strong force of attraction. The atoms as a part of gas have higher energy as those present in the solid products. So, the atoms of the gas wander freely as compared to those in the solid products.

Which of the following is NOT a property of metals?

A - shiny
B - ductile
C - can be solids, liquids, or gases
D - malleable

Answers

Answer:

C - can be solids, liquids, or gases

Explanation:

10.0 g of nickel is cooled to 2.0 °C and
placed into a sample of warm water.
The final temperature of the water and
nickel was 63.4 °C. How much energy
is absorbed by the nickel?
J
CNi = 0.120 g. C
9Ni = [?] J

Answers

Answer:

73.68 J

Explanation:

To find the energy absorbed by nickel, you need to use the following equation:

Q = mcΔT

In this equation,

-----> Q = energy (J)

-----> m = mass (g)

-----> c = specific heat (J/g°C)

-----> ΔT = change in temperature

The change in temperature is found by subtracting the initial temperature from the final temperature. You can plug the given values into the equation and simplify to find the energy absorbed.

m = 10.0 g

c = 0.120 J/g°C

ΔT = 63.4 °C - 2.0 °C = 61.4 °C

Q = mcΔT

Q = (10.0 g)(0.120 J/g°C)(61.4 °C)

Q = 73.68  J

What is the reason why the fermentation products acetate and hydrogen gas (H2) are never abundant in aerobic soils and sediments

Answers

Acetate and hydrogen gas (H2) is never abundant in aerobic soils and sediments because they are tiny, highly reduced molecules that many bacteria that breathe oxygen and nitrates quickly absorb to use as fuel for energy generation. 

Why are acetate and hydrogen gas not abundant in aerobic soils and sediments?

Hydrogen is a substrate for methanogenic archaea and, along with acetate, one of the most significant intermediates in the methanogenic breakdown of organic materials. Numerous methanogenic environments exhibit contributions of H₂ to CH₄ production that are both significantly lower and significantly higher than is considered usual. H₂ is rapidly converted in methanogenic settings due to the simultaneous generation by fermenting and syntrophic bacteria and consumption by methanogenic archaea.

Learn more about archaea here:

https://brainly.com/question/3654264

#SPJ4

Which federal agency makes sure federal wildlife laws are followed?

US Forest Service
US Fish and Wildlife Service
Bureau of Land Management
National Park Service

Answers

Answer:

us fish and wildlife service

Explanation:

the 2nd choice

Answer:

US Fish and Wildlife Service

Guys pleaseeeee help:
- Which element is a member of the alkaline earth metals and has 12 neutrons?
- A burnt piece of toast is covered in this element. It is the fourth most abundant element and makes up many living things.
- Which element is an inert gas found in group VIII that produces a red glow in lights?

Answers

Answer:

Carbon- A burnt piece of toast is covered in this element. It is the fourth most abundant element and makes up many living things.

Magnesium- Which element is a member of the alkaline earth metals and has 12 neutrons?

Neon- Which element is an inert gas found in group VIII that produces a red glow in lights?

how many bananas are equal to 7.50 moles of bananas?​

Answers

Answer:

4.52×10^24

Explanation:

N = n × Na

where; N = no. of bananas

n = no. of moles

Na = Avogadro's constant

Which is 6.02×10^23

N = 7.5 × 6.02×10^23

N =4.515×10^24

Write the formula and determine the percent by mass of the salt in barium hydroxide octahydrate *


(show work)

Answers

Answer:

315.51g/mol

Explanation:

137(33 + (16.00 + 1.01) 2 + 8 [1.01 (2) + 16.00] = 315.51g/mol

(iii) Observe the following diagram and answer the following questions :
X Х
Y
(A) Identify elements X and Y.
(B) Do these elements belong to the same group?
(C) Which element is more electropositive in nature? Why?​

Answers

Ghhfcnjjakwhwbebsiiwuehebsjudyehebwklwiwgehebwkwkkehehrbwkeiehegenkeiehehenekeurhrh

please help me out i will give you brainlist. 0.500 is wrong

Answers

Answer:  b) 0.250 mol

============================================

Work Shown:

Using the periodic table, we see that

1 mole of carbon = 12 grams1 mole of oxygen = 16 grams

These are approximations and these values are often found underneath the atomic symbol. For example, the atomic weight listed under carbon is roughly 12.011 grams. I'm rounding to 2 sig figs in those numbers listed above.

So 1 mole of CO2 is approximately 12+2*16 = 44 grams. The 2 is there since we have 2 oxygens attached to the carbon atom.

-------------------

Since 1 mole of CO2 is 44 grams, we can use that to convert from grams to moles.

11.0 grams of CO2 = (11.0 grams)*(1 mol/44 g) = (11.0/44) mol = 0.250 mol of CO2

In short,

11.0 grams of CO2 = 0.250 mol of CO2

This is approximate.

We don't need to use any of the information in the table.

Answer:

.250

Explanation:

The Venn diagram shown below compares the nuclear reactions in the sun and nuclear power plants.

Picture shows two ovals which overlap in the middle. The oval on the left has the label 'Sun' on top and 'A' within it. The oval on the right has the label 'Nuclear power plants' on top and 'Splitting of atoms' within it. The overlapping portion has the label 'Release of energy' within it.

What process is best described by A?

Destruction of atoms
Fission of atoms
Fusion of atoms
Repulsion of atoms

Answers

The process which is best described by "A" in this Venn diagram is: C. fusion of atoms.

What is nuclear fusion?

Nuclear fusion can be defined as a type of nuclear reaction that involves joining or combining two (2) smaller nuclei of atoms, so as to form a single heavier nucleus accompanied with the release of energy.

Based on the Venn diagram in the image attached below, we can logically deduce that the process which is best described by "A" is fusion of atoms.

Read more on nuclear fusion here: https://brainly.com/question/9903602

#SPJ1

changing the number of _______ makes an atom stable or unstable and creates different isotopes of the same element with a different ______ (pick two that best fits.)
a.) atomic mass
b.) atomic number
c.) protons
d.)neutrons
e.)electrons
f.) ion
g.)neutral

Answers

changing the number of NEUTRONS makes an atom stable or unstable and creates different isotopes of the same element with a different ATOMIC MASS

The neutrons are the neutral sub-atomic particles present in the nucleus. The variation in the number of neutrons produces isotopes that have different atomic mass. Thus, options 1. d and 2. a are correct.

What is an isotope?

An isotope is said to be an atom of an element that have a different atomic mass but the same atomic number due to the variation in the neutrons in the nucleus. The neutrons have a neutral charge that makes the atom stable.

When a neutron is added or lost it makes the nucleus of the atom unstable leading to radioactive decay. The isotopes have the same constant number of protons in their nucleus.

The atomic number of the atom remains the same due to the stable proton number but varies the atomic mass due to the change in the number of neutrons.

Therefore, options d and a. neutrons and atomic mass are the correct blanks.

Learn more about isotopes here:

https://brainly.com/question/1835223

#SPJ2

For what mechanistic reason does g1 of lactase first act as a brønsted acid during catalysis?.

Answers

Answer:  Carboxylation of hydroquinone

A text book is on a desk. If the book weighs 14 N and the area of the book is 0.60 m 2 , what pressure is the book exerting on the desk?

Answers

Answer:

Explanation:

Pressure = Force / Area

F = 14 N

Area = 0.60 m^2

Pressure = 14/0.60

Pressure = 23.3 N

If you are worried about significant digits, the answer is 23

an example of xenon (Xe)

Answers

Answer: i am not sure what you mean but here are some product of xenon stroboscopic lamps, photographic flash lamps, high-intensive arc-lamps for motion picture projection, some lamps used for deep-sea observation, bactericidal lamps, sunbed lamps and high-pressure arc all use this gas. In fact, you probably see xenon lamps on a regular basis and if you want compounds : Xe2F2, XeF4, XeO3, XeF6....

Explanation:

Carbon dioxide and water are produced when ethanol, C2H5OH, is burned in oxygen. The number of moles of CO2 that is produced when burning 6.0 mol of ethanol is

Answers

The number of moles of CO₂ that is produced when burning 6.0 mol of ethanol is 12 mol.

What is Balanced Chemical Equation ?

The balanced chemical equation is the equation in which the number of atoms on the reactant side is equal to the number of atoms on the product side in an equation.

Now we have to write the balanced equation

C₂H₅OH + 3O₂ → 2CO₂ + 3H₂O

We can see that every 1 mole of ethanol we will get 2 mole of CO₂.

So 6.0 mol of ethanol we will get = 6.0 × 2.0

                                                       = 12 mol of CO₂

Thus from the above conclusion we can say that The number of moles of CO₂ that is produced when burning 6.0 mol of ethanol is 12 mol.

Learn more about the Balanced Chemical Equation here: https://brainly.com/question/26694427

#SPJ1

Think about a synthetic material that you use every day. How
could that material be improved to better fit its function?

Answers

explanation: Synthetic fiber or synthetic fibre (in British English; see spelling differences) are fibers made by humans through chemical synthesis, as opposed to natural fibers that are directly derived from living organisms. They are the result of extensive research by scientists to improve upon naturally occurring animal and plant fibers. In general, synthetic fibers are created by extruding fiber-forming materials through spinnerets, forming a fiber. These are called synthetic or artificial fibers. Synthetic fibers are created by a process known as polymerization, which involves combining monomers to make a long chain or polymer. The word polymer comes from a Greek prefix "poly" which means "many" and suffix "mer" which means "single units". (Note: each single unit of a polymer is called a monomer). There are two types of polymerization: linear polymerization and cross-linked polymerization.

explain why dilute trioxosulphate vi acid is not used to prepare carbon 4 oxide from calcium
trioxocarbonate 4​

Answers

Answer:

H2SO4 cannot be used with CaCO3 to produce CO2 gas

Explanation:

Because it does not dissolve in water- it forms a barrier on the surface of the unreacted CaCO3 which prevents any further reaction. A small volume CO2 is produced, this stops in short time.

I hope this helps :)

chemical change grade 10 mind map ​

Answers

Chemical change: A chemical reaction is the change of one chemical substance into another chemical substance. For instance: The rusting of iron, the curdling of milk, the digestion of food, breathing, etc.

What is a chemical reaction?

A chemical reaction results in a chemical change because a new material has entirely different properties from the original substance. In a chemical reaction, atoms rearrange themselves.Reactants are the chemicals that participate in a chemical reaction.Products are the new compounds created as a result of a chemical process.  An illustration of a chemical reaction is burning magnesium in the air to produce magnesium oxide.2Mg(s) + O2(g) △→ 2MgO(s)The magnesium ribbon is cleaned with sandpaper before being burned in the air. This cleans the magnesium ribbon's surface of the basic magnesium carbonate protecting coating.Reactant: Materials that participate in a chemical reaction are referred to as reactants. Mg and O2, as an example.A product is a newly created substance that results from a chemical reaction. Example: MgO.

A chemical reaction is the change of one chemical substance into another chemical substance.

To learn more about chemical reactions, refer to:

https://brainly.com/question/1222323

#SPJ9

Chemical  change is the change  chemical substance is transformed into another chemical substance.It is irreversible in  nature , for example Reaction of medicine in body , milk to curd etc.

What is the difference between chemical and  Physical change?

1)Physical change temporary or reversible in nature but chemical change is irreversible in nature

2)In physical change there no new product is formed but in chemical change there formation of new product takes .

3) Physical change is change sin shape ,size or state for example freezing of water , melting of wax , and example of  Chemical change are Burning of  coal, digestion of food

to learn more about chemical change click here https://brainly.com/question/28089135

#SPJ9

The yellow light given off by a sodium vapor lamp has a wavelength of 589nm. What is the frequency of this radiation? Please show all work.

Answers

Answer:

5.09 x 10⁶ s⁻¹ = 5.09 x 10⁶ Hz

Explanation:

The relation between frequency (ν) and wavelength (λ) is given by:

λ = c/ν

where c is the speed of light (2.998 m/s) and it is a constant.

So, we first convert the wavelength from nanometers (nm) to meters (m) (1 nm = 1 x 10⁻⁹):

λ= 589 nm x (10⁻⁹ nm/1 m) = 5.89 x 10⁻⁷ m

Then, we calculate the frequency from the equation:

λ = c/ν ⇒ ν = c/λ = (2.998 m/s)/(5.89 x 10⁻⁷ m) = 5.09 x 10⁶s⁻¹ = 5.09 x 10⁶ Hz

Thermal expansion occurs when particles of matter move farther apart as temperature increase. True or false ?

Answers

Answer:

true

Explanation:

Which statements describe band theory? Check all that apply.

Electrons all have approximately the same energy.

Electrons move among orbitals of different energies.

Electrons move freely among atoms (delocalized).

Answers

Answer:

b c

Explanation:

right

Answer:

it was A C for me

Explanation:

1.0 mol of ethanol and 1.0 mol of acetic acid are dissolved in water and kept at 100 °C. The volume of the solution is 250 mL. At equilibrium, 0.25 mol of acetic acid has been consumed in producing ethyl acetate. Calculate Kc at 100 °C for the reaction C2H5OH(aq) + CH3CO2H(aq) CH3CO2C2H5(aq) + H2O(l)

Answers

Answer:

Kc = 0.333

Explanation:

First of all we state the equilibrium reaction:

C₂H₅OH(aq) + CH₃CO₂H(aq)  ⇄  CH₃CO₂C₂H₅(aq) + H₂O(l)

Initially we start with 1 mol of alcohol and 1 mol of acid. After the reaction goes complete, 0.25 moles of acid have been consumed. As ratio is 1:1, we also consumed 0.25 moles of alcohol. Then, in the product side we finally produced 0.25 moles of water and 0.25 moles of ethyl acetate.

How many moles are available in the reactant side, after the equilibrium?

1 mol - 0.25 moles (that have been reacted) = 0.75 moles.

To determine Kc, we need molar concentrations, so let's see M in products and reactants:

0.75 mol / 0.25 L = 3 M

0.25 mol / 0.25 L = 1 M

We needed to convert 0.250 mL to L → 0.250 mL . 1L/ 1000mL = 0.250 L

Let's determine expression for Kc:

Kc = [H₂O] . [CH₃CO₂C₂H₅]  / [C₂H₅OH] . [CH₃CO₂H]

1 . 1 / 3 . 3 = 1/9 → 0.333

Other Questions
What is 46 + 47 + 48 + 49 + 50 + 51 + 52 + 53 + 54 = ? libro de matemticas 1 de secundaria pag 108porfavor es para hoy convectional rainfall is accompanied by thunder and lightning. (True, False) a ball has a volume of 2 cubic inches .use the fact that l inch is equal to 2.54 cm to convert this volume to cubic centimeters 5y=2x+5 Y=-x +6( x, y) Select the sentence that uses semicolons correctly.1. Corinne has a bracelet, necklace, and stamp from Albuquerque, a box of postcards from Phoenix, Arizona, and a keychain, t-shirt, and hat from Las Vegas.2. Corinne has a bracelet, necklace, and stamp from Albuquerque, a box of postcards from Phoenix, Arizona; and a keychain, t-shirt, and hat from Las Vegas.3. Corinne has a bracelet, necklace, and stamp from Albuquerque; a box of postcards from Phoenix, Arizona, and a keychain, t-shirt, and hat from Las Vegas.4. Corinne has a bracelet, necklace, and stamp from Albuquerque; a box of postcards from Phoenix, Arizona; and a keychain, t-shirt, and hat from Las Vegas. what does the word counteract mean in the paragraph? act cautiously toward, act before, act with purpose , act against Escoge uno de los derechos de la siguiente lista que estn Escogidos en el cdigo de la niez y adolescencia escribe en una hoja porque es importante que se garantice el derecho que escojiste SI requiere ampliar la informacin REVISA "el cdigo de la niez y la escencia" Discarded materials other than fluids from natural, municipal, agricultural, and industrial sources are called __________.A)hazardous wasteB)air pollutantsC)particulatesD)medical wasteE)solid waste The number of protons plus neutrons in an atom, represented as an average of all naturally occurring forms of the element, is known as_____ Hola me pueden ayudar les doy todas mis puntos Find the value of x.1212x = [?] cual es la enceanza del libro: alicia a travez del espejo de lewis carollpliss Which of the relations has a domain of {-5, 0, 5}?A. {(-5, 5), (0, 5), (5,5)}B. {(0, -5), (0, 0), (0, 5)}C. {(-5, 0), (0, 5), (1, 0)} what is the anwser pls help Please help its due in 5 minutes :( Activity 7: Script writing Direction: Choose one out of four (4) scenarios given below. Then, make a script showing how effective interpersonal and intrapersonal skills are applied in the scenario you have chosen. Be guided by the rubric provided below in making your script. Scenarios: a. Th inking about what course to take in college b. Calling somebody through one of the following media such as telephone, cellular phone, social media applications c. Attending a job interview, through phone and face d. Listening to the Pretoface interaction sidential speech. Write some notes of the non signals that are considered by the speaker.verbal What is the percent by mass of water in the hydrate CoCl 6HO? [tex]\sqrt{2x-3} =5[/tex] Daniel is helping his mom fold the laundry. He folds towels at a constant speed. He made the following table showing how many towels he could fold in a certain number of seconds.HELP ME PLS ASAP PLS PLZ PLZ